Lignin is a fickle molecule to say the least. We’ve worked with lignin for some time and created some interesting composites.
Working with unmodified lignins we’ve seen there are limitations to how much lignin can be loaded into a particular composite. Tensile strength drops off significantly as lignin is added. Lignin builds modulus so the higher the lignin percentage the stiffer the resulting composite. However, as it gets stiffer it also becomes more brittle.
Working with modified lignins we’ve been able to produce composites with 70% or greater lignin loadings. These composites melt readily and I believe that they could be used for 3D printing applications. However, applications would be limited due to the brittleness resulting from high lignin concentrations. Our modified lignins allow for higher lignin concentrations within a particular composite and can be done so economically. Values of $2,000 – $5,000 per metric ton certainly make our products commercially feasible.
It’s good to see Oak Ridge continue to work on lignin.
Lignin Unchained, 3D printable: The Digest’s 2018 Multi-Slide Guide to Engineered Lignin Bioplastics
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